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Record Information

Version

5.0

Status

Expected but not Quantified

Creation Date

2012-09-11 17:49:25 UTC

Update Date

2022-03-07 02:53:20 UTC

HMDB ID

HMDB0032368

Secondary Accession Numbers

HMDB32368

Metabolite Identification

Common Name

Menthyl pyrrolidone carboxylate

Description

Menthyl pyrrolidone carboxylate, also known as 1-menthyl-b-D-glucoside, belongs to the class of organic compounds known as terpene glycosides. These are prenol lipids containing a carbohydrate moiety glycosidically bound to a terpene backbone. Based on a literature review a small amount of articles have been published on Menthyl pyrrolidone carboxylate.

Structure

MOL 3D MOL SDF 3D SDF PDB 3D PDB SMILES InChI

HMDB0032368
     RDKit          3D
Menthyl pyrrolidone carboxylate
 52 53  0  0  0  0  0  0  0  0999 V2000
   -2.7275    2.6971    0.2609 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.6268    1.6607    0.4054 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.3361    1.5272    1.8820 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.0510    0.3406   -0.2146 C   0  0  2  0  0  0  0  0  0  0  0  0
   -3.2970   -0.1229    0.5091 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.8475   -1.2982   -0.2715 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.8069   -2.3915   -0.1898 C   0  0  1  0  0  0  0  0  0  0  0  0
   -3.2365   -3.6402   -0.9332 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.4820   -1.9793   -0.7340 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.9501   -0.6876   -0.1536 C   0  0  1  0  0  0  0  0  0  0  0  0
    0.0851   -0.2638   -0.9535 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.2864   -0.0753   -0.3324 C   0  0  2  0  0  0  0  0  0  0  0  0
    1.8087    1.1714   -0.5560 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.8719    1.4218    0.3414 C   0  0  2  0  0  0  0  0  0  0  0  0
    3.4239    2.7799   -0.0218 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.4855    3.1416    0.7989 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.8928    0.3302    0.2692 C   0  0  1  0  0  0  0  0  0  0  0  0
    3.8430   -0.5317    1.3677 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.6541   -0.4902   -0.9688 C   0  0  2  0  0  0  0  0  0  0  0  0
    3.7353    0.3451   -2.0834 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.2647   -1.1109   -0.9154 C   0  0  1  0  0  0  0  0  0  0  0  0
    2.3434   -2.2244   -0.0903 O   0  0  0  0  0  0  0  0  0  0  0  0
   -2.2551    3.6982    0.0468 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.3465    2.4403   -0.6042 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.3522    2.7822    1.1681 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7472    2.0242   -0.1447 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.2017    1.1430    2.4201 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.0782    2.5454    2.2468 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.4383    0.8871    2.0232 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.3438    0.5306   -1.2684 H   0  0  0  0  0  0  0  0  0  0  0  0
   -4.0184    0.6917    0.4885 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.0680   -0.4709    1.5301 H   0  0  0  0  0  0  0  0  0  0  0  0
   -4.0297   -1.0453   -1.3211 H   0  0  0  0  0  0  0  0  0  0  0  0
   -4.7612   -1.6720    0.2199 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.6950   -2.6407    0.9003 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.9846   -3.4649   -2.0148 H   0  0  0  0  0  0  0  0  0  0  0  0
   -4.3283   -3.8231   -0.8300 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.6465   -4.5002   -0.5965 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7795   -2.8106   -0.5927 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.5869   -1.8097   -1.8358 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.6641   -0.8071    0.9151 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.2948   -0.2747    0.7527 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.4979    1.4770    1.3921 H   0  0  0  0  0  0  0  0  0  0  0  0
    3.6765    2.8630   -1.0867 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.5912    3.5117    0.1656 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.6261    2.4325    1.4859 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.9113    0.7800    0.1905 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.5074   -1.2503    1.1800 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.4142   -1.2881   -1.0872 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.5779    0.8501   -2.0332 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.9165   -1.4020   -1.9226 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.9779   -1.9969    0.7960 H   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0
  2  3  1  0
  2  4  1  0
  4  5  1  0
  5  6  1  0
  6  7  1  0
  7  8  1  0
  7  9  1  0
  9 10  1  0
 10 11  1  0
 11 12  1  0
 12 13  1  0
 13 14  1  0
 14 15  1  0
 15 16  1  0
 14 17  1  0
 17 18  1  0
 17 19  1  0
 19 20  1  0
 19 21  1  0
 21 22  1  0
 10  4  1  0
 21 12  1  0
  1 23  1  0
  1 24  1  0
  1 25  1  0
  2 26  1  0
  3 27  1  0
  3 28  1  0
  3 29  1  0
  4 30  1  6
  5 31  1  0
  5 32  1  0
  6 33  1  0
  6 34  1  0
  7 35  1  1
  8 36  1  0
  8 37  1  0
  8 38  1  0
  9 39  1  0
  9 40  1  0
 10 41  1  1
 12 42  1  1
 14 43  1  1
 15 44  1  0
 15 45  1  0
 16 46  1  0
 17 47  1  6
 18 48  1  0
 19 49  1  6
 20 50  1  0
 21 51  1  6
 22 52  1  0
M  END


  Mrv0541 02241212462D          

 22 23  0  0  0  0            999 V2000
   -4.2321    1.6500    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -3.5176    1.2375    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.5176    0.4125    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   -4.2321    0.0000    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -4.9466    0.4125    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -4.9466    1.2375    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -4.2321    2.4750    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -4.2321   -0.8250    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -4.9466   -1.2375    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.5176   -1.2375    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.5657    0.7145    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7407    0.7145    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -0.3281    0.0000    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   -0.7406   -0.7145    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -1.5656   -0.7145    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   -1.9781    0.0000    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   -2.8031    0.0000    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.9782   -1.4290    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.3281    1.4289    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.4969    0.0000    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.3281   -1.4290    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.4969    1.4289    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  1  6  1  0  0  0  0
  2  3  1  0  0  0  0
  3  4  1  0  0  0  0
  4  5  1  0  0  0  0
  5  6  1  0  0  0  0
  1  7  1  1  0  0  0
  4  8  1  6  0  0  0
  8  9  1  0  0  0  0
  8 10  1  0  0  0  0
  3 17  1  1  0  0  0
 11 12  1  0  0  0  0
 11 16  1  0  0  0  0
 12 13  1  0  0  0  0
 12 19  1  6  0  0  0
 14 13  1  0  0  0  0
 13 20  1  1  0  0  0
 14 15  1  0  0  0  0
 14 21  1  6  0  0  0
 15 16  1  0  0  0  0
 15 18  1  1  0  0  0
 16 17  1  6  0  0  0
 19 22  1  0  0  0  0
M  END
> <DATABASE_ID>
HMDB0032368

> <DATABASE_NAME>
hmdb

> <SMILES>
CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O

> <INCHI_IDENTIFIER>
InChI=1S/C16H30O6/c1-8(2)10-5-4-9(3)6-11(10)21-16-15(20)14(19)13(18)12(7-17)22-16/h8-20H,4-7H2,1-3H3/t9-,10+,11-,12-,13-,14+,15-,16-/m1/s1

> <INCHI_KEY>
GZSDZJZIZBGBON-NZZARTGWSA-N

> <FORMULA>
C16H30O6

> <MOLECULAR_WEIGHT>
318.4058

> <EXACT_MASS>
318.204238692

> <JCHEM_ACCEPTOR_COUNT>
6

> <JCHEM_AVERAGE_POLARIZABILITY>
34.44122795210587

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
4

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
1

> <JCHEM_IUPAC>
(2R,3S,4S,5R,6R)-2-(hydroxymethyl)-6-{[(1R,2S,5R)-5-methyl-2-(propan-2-yl)cyclohexyl]oxy}oxane-3,4,5-triol

> <ALOGPS_LOGP>
0.47

> <JCHEM_LOGP>
0.8934375013333334

> <ALOGPS_LOGS>
-1.42

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
2

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
13.200090355731682

> <JCHEM_PKA_STRONGEST_ACIDIC>
12.21056213276569

> <JCHEM_PKA_STRONGEST_BASIC>
-2.981083542786302

> <JCHEM_POLAR_SURFACE_AREA>
99.38000000000001

> <JCHEM_REFRACTIVITY>
79.8586

> <JCHEM_ROTATABLE_BOND_COUNT>
4

> <JCHEM_RULE_OF_FIVE>
1

> <ALOGPS_SOLUBILITY>
1.22e+01 g/l

> <JCHEM_TRADITIONAL_IUPAC>
(-)-menthyl β-D-glucoside

> <JCHEM_VEBER_RULE>
0

$$$$

HMDB0032368
     RDKit          3D
Menthyl pyrrolidone carboxylate
 52 53  0  0  0  0  0  0  0  0999 V2000
   -2.7275    2.6971    0.2609 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.6268    1.6607    0.4054 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.3361    1.5272    1.8820 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.0510    0.3406   -0.2146 C   0  0  2  0  0  0  0  0  0  0  0  0
   -3.2970   -0.1229    0.5091 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.8475   -1.2982   -0.2715 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.8069   -2.3915   -0.1898 C   0  0  1  0  0  0  0  0  0  0  0  0
   -3.2365   -3.6402   -0.9332 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.4820   -1.9793   -0.7340 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.9501   -0.6876   -0.1536 C   0  0  1  0  0  0  0  0  0  0  0  0
    0.0851   -0.2638   -0.9535 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.2864   -0.0753   -0.3324 C   0  0  2  0  0  0  0  0  0  0  0  0
    1.8087    1.1714   -0.5560 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.8719    1.4218    0.3414 C   0  0  2  0  0  0  0  0  0  0  0  0
    3.4239    2.7799   -0.0218 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.4855    3.1416    0.7989 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.8928    0.3302    0.2692 C   0  0  1  0  0  0  0  0  0  0  0  0
    3.8430   -0.5317    1.3677 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.6541   -0.4902   -0.9688 C   0  0  2  0  0  0  0  0  0  0  0  0
    3.7353    0.3451   -2.0834 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.2647   -1.1109   -0.9154 C   0  0  1  0  0  0  0  0  0  0  0  0
    2.3434   -2.2244   -0.0903 O   0  0  0  0  0  0  0  0  0  0  0  0
   -2.2551    3.6982    0.0468 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.3465    2.4403   -0.6042 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.3522    2.7822    1.1681 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7472    2.0242   -0.1447 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.2017    1.1430    2.4201 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.0782    2.5454    2.2468 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.4383    0.8871    2.0232 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.3438    0.5306   -1.2684 H   0  0  0  0  0  0  0  0  0  0  0  0
   -4.0184    0.6917    0.4885 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.0680   -0.4709    1.5301 H   0  0  0  0  0  0  0  0  0  0  0  0
   -4.0297   -1.0453   -1.3211 H   0  0  0  0  0  0  0  0  0  0  0  0
   -4.7612   -1.6720    0.2199 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.6950   -2.6407    0.9003 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.9846   -3.4649   -2.0148 H   0  0  0  0  0  0  0  0  0  0  0  0
   -4.3283   -3.8231   -0.8300 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.6465   -4.5002   -0.5965 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7795   -2.8106   -0.5927 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.5869   -1.8097   -1.8358 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.6641   -0.8071    0.9151 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.2948   -0.2747    0.7527 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.4979    1.4770    1.3921 H   0  0  0  0  0  0  0  0  0  0  0  0
    3.6765    2.8630   -1.0867 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.5912    3.5117    0.1656 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.6261    2.4325    1.4859 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.9113    0.7800    0.1905 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.5074   -1.2503    1.1800 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.4142   -1.2881   -1.0872 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.5779    0.8501   -2.0332 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.9165   -1.4020   -1.9226 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.9779   -1.9969    0.7960 H   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0
  2  3  1  0
  2  4  1  0
  4  5  1  0
  5  6  1  0
  6  7  1  0
  7  8  1  0
  7  9  1  0
  9 10  1  0
 10 11  1  0
 11 12  1  0
 12 13  1  0
 13 14  1  0
 14 15  1  0
 15 16  1  0
 14 17  1  0
 17 18  1  0
 17 19  1  0
 19 20  1  0
 19 21  1  0
 21 22  1  0
 10  4  1  0
 21 12  1  0
  1 23  1  0
  1 24  1  0
  1 25  1  0
  2 26  1  0
  3 27  1  0
  3 28  1  0
  3 29  1  0
  4 30  1  6
  5 31  1  0
  5 32  1  0
  6 33  1  0
  6 34  1  0
  7 35  1  1
  8 36  1  0
  8 37  1  0
  8 38  1  0
  9 39  1  0
  9 40  1  0
 10 41  1  1
 12 42  1  1
 14 43  1  1
 15 44  1  0
 15 45  1  0
 16 46  1  0
 17 47  1  6
 18 48  1  0
 19 49  1  6
 20 50  1  0
 21 51  1  6
 22 52  1  0
M  END

HEADER    PROTEIN                                 24-FEB-12   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   24-FEB-12         0                                  
HETATM    1  C   UNK     0      -7.900   3.080   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0      -6.566   2.310   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0      -6.566   0.770   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0      -7.900   0.000   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0      -9.234   0.770   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0      -9.234   2.310   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0      -7.900   4.620   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0      -7.900  -1.540   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0      -9.234  -2.310   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0      -6.566  -2.310   0.000  0.00  0.00           C+0
HETATM   11  O   UNK     0      -2.923   1.334   0.000  0.00  0.00           O+0
HETATM   12  C   UNK     0      -1.383   1.334   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0      -0.612   0.000   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0      -1.382  -1.334   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0      -2.922  -1.334   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0      -3.692   0.000   0.000  0.00  0.00           C+0
HETATM   17  O   UNK     0      -5.232   0.000   0.000  0.00  0.00           O+0
HETATM   18  O   UNK     0      -3.693  -2.667   0.000  0.00  0.00           O+0
HETATM   19  C   UNK     0      -0.612   2.667   0.000  0.00  0.00           C+0
HETATM   20  O   UNK     0       0.928   0.000   0.000  0.00  0.00           O+0
HETATM   21  O   UNK     0      -0.612  -2.667   0.000  0.00  0.00           O+0
HETATM   22  O   UNK     0       0.928   2.667   0.000  0.00  0.00           O+0
CONECT    1    2    6    7                                                  
CONECT    2    1    3                                                       
CONECT    3    2    4   17                                                  
CONECT    4    3    5    8                                                  
CONECT    5    4    6                                                       
CONECT    6    1    5                                                       
CONECT    7    1                                                            
CONECT    8    4    9   10                                                  
CONECT    9    8                                                            
CONECT   10    8                                                            
CONECT   11   12   16                                                       
CONECT   12   11   13   19                                                  
CONECT   13   12   14   20                                                  
CONECT   14   13   15   21                                                  
CONECT   15   14   16   18                                                  
CONECT   16   11   15   17                                                  
CONECT   17    3   16                                                       
CONECT   18   15                                                            
CONECT   19   12   22                                                       
CONECT   20   13                                                            
CONECT   21   14                                                            
CONECT   22   19                                                            
MASTER        0    0    0    0    0    0    0    0   22    0   46    0
END

COMPND    HMDB0032368
HETATM    1  C1  UNL     1      -2.727   2.697   0.261  1.00  0.00           C  
HETATM    2  C2  UNL     1      -1.627   1.661   0.405  1.00  0.00           C  
HETATM    3  C3  UNL     1      -1.336   1.527   1.882  1.00  0.00           C  
HETATM    4  C4  UNL     1      -2.051   0.341  -0.215  1.00  0.00           C  
HETATM    5  C5  UNL     1      -3.297  -0.123   0.509  1.00  0.00           C  
HETATM    6  C6  UNL     1      -3.847  -1.298  -0.271  1.00  0.00           C  
HETATM    7  C7  UNL     1      -2.807  -2.391  -0.190  1.00  0.00           C  
HETATM    8  C8  UNL     1      -3.237  -3.640  -0.933  1.00  0.00           C  
HETATM    9  C9  UNL     1      -1.482  -1.979  -0.734  1.00  0.00           C  
HETATM   10  C10 UNL     1      -0.950  -0.688  -0.154  1.00  0.00           C  
HETATM   11  O1  UNL     1       0.085  -0.264  -0.954  1.00  0.00           O  
HETATM   12  C11 UNL     1       1.286  -0.075  -0.332  1.00  0.00           C  
HETATM   13  O2  UNL     1       1.809   1.171  -0.556  1.00  0.00           O  
HETATM   14  C12 UNL     1       2.872   1.422   0.341  1.00  0.00           C  
HETATM   15  C13 UNL     1       3.424   2.780  -0.022  1.00  0.00           C  
HETATM   16  O3  UNL     1       4.486   3.142   0.799  1.00  0.00           O  
HETATM   17  C14 UNL     1       3.893   0.330   0.269  1.00  0.00           C  
HETATM   18  O4  UNL     1       3.843  -0.532   1.368  1.00  0.00           O  
HETATM   19  C15 UNL     1       3.654  -0.490  -0.969  1.00  0.00           C  
HETATM   20  O5  UNL     1       3.735   0.345  -2.083  1.00  0.00           O  
HETATM   21  C16 UNL     1       2.265  -1.111  -0.915  1.00  0.00           C  
HETATM   22  O6  UNL     1       2.343  -2.224  -0.090  1.00  0.00           O  
HETATM   23  H1  UNL     1      -2.255   3.698   0.047  1.00  0.00           H  
HETATM   24  H2  UNL     1      -3.346   2.440  -0.604  1.00  0.00           H  
HETATM   25  H3  UNL     1      -3.352   2.782   1.168  1.00  0.00           H  
HETATM   26  H4  UNL     1      -0.747   2.024  -0.145  1.00  0.00           H  
HETATM   27  H5  UNL     1      -2.202   1.143   2.420  1.00  0.00           H  
HETATM   28  H6  UNL     1      -1.078   2.545   2.247  1.00  0.00           H  
HETATM   29  H7  UNL     1      -0.438   0.887   2.023  1.00  0.00           H  
HETATM   30  H8  UNL     1      -2.344   0.531  -1.268  1.00  0.00           H  
HETATM   31  H9  UNL     1      -4.018   0.692   0.489  1.00  0.00           H  
HETATM   32  H10 UNL     1      -3.068  -0.471   1.530  1.00  0.00           H  
HETATM   33  H11 UNL     1      -4.030  -1.045  -1.321  1.00  0.00           H  
HETATM   34  H12 UNL     1      -4.761  -1.672   0.220  1.00  0.00           H  
HETATM   35  H13 UNL     1      -2.695  -2.641   0.900  1.00  0.00           H  
HETATM   36  H14 UNL     1      -2.985  -3.465  -2.015  1.00  0.00           H  
HETATM   37  H15 UNL     1      -4.328  -3.823  -0.830  1.00  0.00           H  
HETATM   38  H16 UNL     1      -2.646  -4.500  -0.596  1.00  0.00           H  
HETATM   39  H17 UNL     1      -0.780  -2.811  -0.593  1.00  0.00           H  
HETATM   40  H18 UNL     1      -1.587  -1.810  -1.836  1.00  0.00           H  
HETATM   41  H19 UNL     1      -0.664  -0.807   0.915  1.00  0.00           H  
HETATM   42  H20 UNL     1       1.295  -0.275   0.753  1.00  0.00           H  
HETATM   43  H21 UNL     1       2.498   1.477   1.392  1.00  0.00           H  
HETATM   44  H22 UNL     1       3.677   2.863  -1.087  1.00  0.00           H  
HETATM   45  H23 UNL     1       2.591   3.512   0.166  1.00  0.00           H  
HETATM   46  H24 UNL     1       4.626   2.432   1.486  1.00  0.00           H  
HETATM   47  H25 UNL     1       4.911   0.780   0.190  1.00  0.00           H  
HETATM   48  H26 UNL     1       4.507  -1.250   1.180  1.00  0.00           H  
HETATM   49  H27 UNL     1       4.414  -1.288  -1.087  1.00  0.00           H  
HETATM   50  H28 UNL     1       4.578   0.850  -2.033  1.00  0.00           H  
HETATM   51  H29 UNL     1       1.916  -1.402  -1.923  1.00  0.00           H  
HETATM   52  H30 UNL     1       1.978  -1.997   0.796  1.00  0.00           H  
CONECT    1    2   23   24   25
CONECT    2    3    4   26
CONECT    3   27   28   29
CONECT    4    5   10   30
CONECT    5    6   31   32
CONECT    6    7   33   34
CONECT    7    8    9   35
CONECT    8   36   37   38
CONECT    9   10   39   40
CONECT   10   11   41
CONECT   11   12
CONECT   12   13   21   42
CONECT   13   14
CONECT   14   15   17   43
CONECT   15   16   44   45
CONECT   16   46
CONECT   17   18   19   47
CONECT   18   48
CONECT   19   20   21   49
CONECT   20   50
CONECT   21   22   51
CONECT   22   52
END

HMDB0032368
     RDKit          3D
Menthyl pyrrolidone carboxylate
 52 53  0  0  0  0  0  0  0  0999 V2000
   -2.7275    2.6971    0.2609 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.6268    1.6607    0.4054 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.3361    1.5272    1.8820 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.0510    0.3406   -0.2146 C   0  0  2  0  0  0  0  0  0  0  0  0
   -3.2970   -0.1229    0.5091 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.8475   -1.2982   -0.2715 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.8069   -2.3915   -0.1898 C   0  0  1  0  0  0  0  0  0  0  0  0
   -3.2365   -3.6402   -0.9332 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.4820   -1.9793   -0.7340 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.9501   -0.6876   -0.1536 C   0  0  1  0  0  0  0  0  0  0  0  0
    0.0851   -0.2638   -0.9535 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.2864   -0.0753   -0.3324 C   0  0  2  0  0  0  0  0  0  0  0  0
    1.8087    1.1714   -0.5560 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.8719    1.4218    0.3414 C   0  0  2  0  0  0  0  0  0  0  0  0
    3.4239    2.7799   -0.0218 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.4855    3.1416    0.7989 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.8928    0.3302    0.2692 C   0  0  1  0  0  0  0  0  0  0  0  0
    3.8430   -0.5317    1.3677 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.6541   -0.4902   -0.9688 C   0  0  2  0  0  0  0  0  0  0  0  0
    3.7353    0.3451   -2.0834 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.2647   -1.1109   -0.9154 C   0  0  1  0  0  0  0  0  0  0  0  0
    2.3434   -2.2244   -0.0903 O   0  0  0  0  0  0  0  0  0  0  0  0
   -2.2551    3.6982    0.0468 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.3465    2.4403   -0.6042 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.3522    2.7822    1.1681 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7472    2.0242   -0.1447 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.2017    1.1430    2.4201 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.0782    2.5454    2.2468 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.4383    0.8871    2.0232 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.3438    0.5306   -1.2684 H   0  0  0  0  0  0  0  0  0  0  0  0
   -4.0184    0.6917    0.4885 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.0680   -0.4709    1.5301 H   0  0  0  0  0  0  0  0  0  0  0  0
   -4.0297   -1.0453   -1.3211 H   0  0  0  0  0  0  0  0  0  0  0  0
   -4.7612   -1.6720    0.2199 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.6950   -2.6407    0.9003 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.9846   -3.4649   -2.0148 H   0  0  0  0  0  0  0  0  0  0  0  0
   -4.3283   -3.8231   -0.8300 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.6465   -4.5002   -0.5965 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7795   -2.8106   -0.5927 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.5869   -1.8097   -1.8358 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.6641   -0.8071    0.9151 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.2948   -0.2747    0.7527 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.4979    1.4770    1.3921 H   0  0  0  0  0  0  0  0  0  0  0  0
    3.6765    2.8630   -1.0867 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.5912    3.5117    0.1656 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.6261    2.4325    1.4859 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.9113    0.7800    0.1905 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.5074   -1.2503    1.1800 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.4142   -1.2881   -1.0872 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.5779    0.8501   -2.0332 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.9165   -1.4020   -1.9226 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.9779   -1.9969    0.7960 H   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0
  2  3  1  0
  2  4  1  0
  4  5  1  0
  5  6  1  0
  6  7  1  0
  7  8  1  0
  7  9  1  0
  9 10  1  0
 10 11  1  0
 11 12  1  0
 12 13  1  0
 13 14  1  0
 14 15  1  0
 15 16  1  0
 14 17  1  0
 17 18  1  0
 17 19  1  0
 19 20  1  0
 19 21  1  0
 21 22  1  0
 10  4  1  0
 21 12  1  0
  1 23  1  0
  1 24  1  0
  1 25  1  0
  2 26  1  0
  3 27  1  0
  3 28  1  0
  3 29  1  0
  4 30  1  6
  5 31  1  0
  5 32  1  0
  6 33  1  0
  6 34  1  0
  7 35  1  1
  8 36  1  0
  8 37  1  0
  8 38  1  0
  9 39  1  0
  9 40  1  0
 10 41  1  1
 12 42  1  1
 14 43  1  1
 15 44  1  0
 15 45  1  0
 16 46  1  0
 17 47  1  6
 18 48  1  0
 19 49  1  6
 20 50  1  0
 21 51  1  6
 22 52  1  0
M  END

View in JSmol View NMR Assignments View Stereo Labels

Synonyms

Value	Source
(-)-Menthyl O-beta-glucopyranoside	ChEBI
(-)-Menthyl O-beta-D-glucoside	ChEBI
(-)-Menthyl O-b-glucopyranoside	Generator
(-)-Menthyl O-β-glucopyranoside	Generator
(-)-Menthyl O-b-D-glucoside	Generator
(-)-Menthyl O-β-D-glucoside	Generator
Menthyl pyrrolidone carboxylic acid	Generator
(-)-Menthyl b-D-glucoside	HMDB
(-)-Menthyl β-D-glucoside	HMDB
1-Menthyl-b-D-glucoside	HMDB
1-Menthyl-β-D-glucoside	HMDB

Chemical Formula

C₁₆H₃₀O₆

Average Molecular Weight

318.4058

Monoisotopic Molecular Weight

318.204238692

IUPAC Name

(2R,3S,4S,5R,6R)-2-(hydroxymethyl)-6-{[(1R,2S,5R)-5-methyl-2-(propan-2-yl)cyclohexyl]oxy}oxane-3,4,5-triol

Traditional Name

(-)-menthyl β-D-glucoside

CAS Registry Number

52528-10-6

SMILES

CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O

InChI Identifier

InChI=1S/C16H30O6/c1-8(2)10-5-4-9(3)6-11(10)21-16-15(20)14(19)13(18)12(7-17)22-16/h8-20H,4-7H2,1-3H3/t9-,10+,11-,12-,13-,14+,15-,16-/m1/s1

InChI Key

GZSDZJZIZBGBON-NZZARTGWSA-N

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as terpene glycosides. These are prenol lipids containing a carbohydrate moiety glycosidically bound to a terpene backbone.

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Prenol lipids

Sub Class

Terpene glycosides

Direct Parent

Terpene glycosides

Alternative Parents

Substituents

Terpene glycoside
Glycosyl compound
O-glycosyl compound
Monocyclic monoterpenoid
Monoterpenoid
P-menthane monoterpenoid
Oxane
Monosaccharide
Secondary alcohol
Polyol
Acetal
Oxacycle
Organoheterocyclic compound
Primary alcohol
Organooxygen compound
Hydrocarbon derivative
Alcohol
Organic oxygen compound
Aliphatic heteromonocyclic compound

Molecular Framework

Aliphatic heteromonocyclic compounds

External Descriptors

beta-D-glucoside (CHEBI:15411 )
Menthane monoterpenoids (C03962 )
Menthane monoterpenoids (LMPR0102090060 )

Ontology

Physiological effect

Not Available

Disposition

Biological location

Cellular substructure

Source

Exogenous

Exogenous (HMDB: HMDB0032368)

Endogenous

Endogenous (HMDB: HMDB0032368)

Process

Not Available

Role

Not Available

Physical Properties

State

Not Available

Experimental Molecular Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Experimental Chromatographic Properties

Not Available

Predicted Molecular Properties

Property	Value	Source
Water Solubility	12.2 g/L	ALOGPS
logP	0.47	ALOGPS
logP	0.89	ChemAxon
logS	-1.4	ALOGPS
pKa (Strongest Acidic)	12.21	ChemAxon
pKa (Strongest Basic)	-3	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	6	ChemAxon
Hydrogen Donor Count	4	ChemAxon
Polar Surface Area	99.38 Å²	ChemAxon
Rotatable Bond Count	4	ChemAxon
Refractivity	79.86 m³·mol⁻¹	ChemAxon
Polarizability	34.44 Å³	ChemAxon
Number of Rings	2	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	Yes	ChemAxon
Ghose Filter	Yes	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	No	ChemAxon

Predicted Chromatographic Properties

Predicted Collision Cross Sections

Predictor	Adduct Type	CCS Value (Å²)	Reference
DarkChem	[M+H]+	174.511	31661259
DarkChem	[M-H]-	169.496	31661259
DeepCCS	[M+H]+	174.996	30932474
DeepCCS	[M-H]-	172.6	30932474
DeepCCS	[M-2H]-	205.975	30932474
DeepCCS	[M+Na]+	180.908	30932474
AllCCS	[M+H]+	179.3	32859911
AllCCS	[M+H-H2O]+	176.3	32859911
AllCCS	[M+NH4]+	182.0	32859911
AllCCS	[M+Na]+	182.8	32859911
AllCCS	[M-H]-	177.2	32859911
AllCCS	[M+Na-2H]-	177.7	32859911
AllCCS	[M+HCOO]-	178.5	32859911

Predicted Retention Times

Underivatized

Chromatographic Method	Retention Time	Reference
Measured using a Waters Acquity ultraperformance liquid chromatography (UPLC) ethylene-bridged hybrid (BEH) C18 column (100 mm × 2.1 mm; 1.7 μmparticle diameter). Predicted by Afia on May 17, 2022. Predicted by Afia on May 17, 2022.	2.72 minutes	32390414
Predicted by Siyang on May 30, 2022	11.6579 minutes	33406817
Predicted by Siyang using ReTip algorithm on June 8, 2022	2.2 minutes	32390414
AjsUoB = Accucore 150 Amide HILIC with 10mM Ammonium Formate, 0.1% Formic Acid	55.0 seconds	40023050
Fem_Long = Waters ACQUITY UPLC HSS T3 C18 with Water:MeOH and 0.1% Formic Acid	2104.9 seconds	40023050
Fem_Lipids = Ascentis Express C18 with (60:40 water:ACN):(90:10 IPA:ACN) and 10mM NH4COOH + 0.1% Formic Acid	208.8 seconds	40023050
Life_Old = Waters ACQUITY UPLC BEH C18 with Water:(20:80 acetone:ACN) and 0.1% Formic Acid	136.9 seconds	40023050
Life_New = RP Waters ACQUITY UPLC HSS T3 C18 with Water:(30:70 MeOH:ACN) and 0.1% Formic Acid	162.2 seconds	40023050
RIKEN = Waters ACQUITY UPLC BEH C18 with Water:ACN and 0.1% Formic Acid	140.1 seconds	40023050
Eawag_XBridgeC18 = XBridge C18 3.5u 2.1x50 mm with Water:MeOH and 0.1% Formic Acid	476.3 seconds	40023050
BfG_NTS_RP1 =Agilent Zorbax Eclipse Plus C18 (2.1 mm x 150 mm, 3.5 um) with Water:ACN and 0.1% Formic Acid	507.4 seconds	40023050
HILIC_BDD_2 = Merck SeQuant ZIC-HILIC with ACN(0.1% formic acid):water(16 mM ammonium formate)	78.6 seconds	40023050
UniToyama_Atlantis = RP Waters Atlantis T3 (2.1 x 150 mm, 5 um) with ACN:Water and 0.1% Formic Acid	851.8 seconds	40023050
BDD_C18 = Hypersil Gold 1.9µm C18 with Water:ACN and 0.1% Formic Acid	436.4 seconds	40023050
UFZ_Phenomenex = Kinetex Core-Shell C18 2.6 um, 3.0 x 100 mm, Phenomenex with Water:MeOH and 0.1% Formic Acid	1323.0 seconds	40023050
SNU_RIKEN_POS = Waters ACQUITY UPLC BEH C18 with Water:ACN and 0.1% Formic Acid	277.3 seconds	40023050
RPMMFDA = Waters ACQUITY UPLC BEH C18 with Water:ACN and 0.1% Formic Acid	337.6 seconds	40023050
MTBLS87 = Merck SeQuant ZIC-pHILIC column with ACN:Water and :ammonium carbonate	244.7 seconds	40023050
KI_GIAR_zic_HILIC_pH2_7 = Merck SeQuant ZIC-HILIC with ACN:Water and 0.1% FA	151.4 seconds	40023050
Meister zic-pHILIC pH9.3 = Merck SeQuant ZIC-pHILIC column with ACN:Water 5mM NH4Ac pH9.3 and 5mM ammonium acetate in water	36.1 seconds	40023050

Predicted Kovats Retention Indices

Underivatized

Metabolite	SMILES	Kovats RI Value	Column Type	Reference
Menthyl pyrrolidone carboxylate	CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O	3171.1	Standard polar	33892256
Menthyl pyrrolidone carboxylate	CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O	2368.4	Standard non polar	33892256
Menthyl pyrrolidone carboxylate	CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O	2460.2	Semi standard non polar	33892256

Derivatized

Derivative Name / Structure	SMILES	Kovats RI Value	Column Type	Reference
Menthyl pyrrolidone carboxylate,1TMS,isomer #1	CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O[C@@H]1O[C@H](CO[Si](C)(C)C)[C@@H](O)[C@H](O)[C@H]1O	2284.0	Semi standard non polar	33892256
Menthyl pyrrolidone carboxylate,1TMS,isomer #2	CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O[C@@H]1O[C@H](CO)[C@@H](O[Si](C)(C)C)[C@H](O)[C@H]1O	2266.4	Semi standard non polar	33892256
Menthyl pyrrolidone carboxylate,1TMS,isomer #3	CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O[Si](C)(C)C)[C@H]1O	2274.3	Semi standard non polar	33892256
Menthyl pyrrolidone carboxylate,1TMS,isomer #4	CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O[Si](C)(C)C	2262.7	Semi standard non polar	33892256
Menthyl pyrrolidone carboxylate,2TMS,isomer #1	CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O[C@@H]1O[C@H](CO[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H](O)[C@H]1O	2317.7	Semi standard non polar	33892256
Menthyl pyrrolidone carboxylate,2TMS,isomer #2	CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O[C@@H]1O[C@H](CO[Si](C)(C)C)[C@@H](O)[C@H](O[Si](C)(C)C)[C@H]1O	2341.4	Semi standard non polar	33892256
Menthyl pyrrolidone carboxylate,2TMS,isomer #3	CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O[C@@H]1O[C@H](CO[Si](C)(C)C)[C@@H](O)[C@H](O)[C@H]1O[Si](C)(C)C	2306.2	Semi standard non polar	33892256
Menthyl pyrrolidone carboxylate,2TMS,isomer #4	CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O[C@@H]1O[C@H](CO)[C@@H](O[Si](C)(C)C)[C@H](O[Si](C)(C)C)[C@H]1O	2315.9	Semi standard non polar	33892256
Menthyl pyrrolidone carboxylate,2TMS,isomer #5	CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O[C@@H]1O[C@H](CO)[C@@H](O[Si](C)(C)C)[C@H](O)[C@H]1O[Si](C)(C)C	2319.5	Semi standard non polar	33892256
Menthyl pyrrolidone carboxylate,2TMS,isomer #6	CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O[Si](C)(C)C)[C@H]1O[Si](C)(C)C	2313.7	Semi standard non polar	33892256
Menthyl pyrrolidone carboxylate,3TMS,isomer #1	CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O[C@@H]1O[C@H](CO[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H](O[Si](C)(C)C)[C@H]1O	2339.0	Semi standard non polar	33892256
Menthyl pyrrolidone carboxylate,3TMS,isomer #2	CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O[C@@H]1O[C@H](CO[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H](O)[C@H]1O[Si](C)(C)C	2354.8	Semi standard non polar	33892256
Menthyl pyrrolidone carboxylate,3TMS,isomer #3	CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O[C@@H]1O[C@H](CO[Si](C)(C)C)[C@@H](O)[C@H](O[Si](C)(C)C)[C@H]1O[Si](C)(C)C	2332.6	Semi standard non polar	33892256
Menthyl pyrrolidone carboxylate,3TMS,isomer #4	CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O[C@@H]1O[C@H](CO)[C@@H](O[Si](C)(C)C)[C@H](O[Si](C)(C)C)[C@H]1O[Si](C)(C)C	2320.5	Semi standard non polar	33892256
Menthyl pyrrolidone carboxylate,4TMS,isomer #1	CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O[C@@H]1O[C@H](CO[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H](O[Si](C)(C)C)[C@H]1O[Si](C)(C)C	2325.3	Semi standard non polar	33892256
Menthyl pyrrolidone carboxylate,1TBDMS,isomer #1	CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O[C@@H]1O[C@H](CO[Si](C)(C)C(C)(C)C)[C@@H](O)[C@H](O)[C@H]1O	2505.6	Semi standard non polar	33892256
Menthyl pyrrolidone carboxylate,1TBDMS,isomer #2	CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O[C@@H]1O[C@H](CO)[C@@H](O[Si](C)(C)C(C)(C)C)[C@H](O)[C@H]1O	2505.1	Semi standard non polar	33892256
Menthyl pyrrolidone carboxylate,1TBDMS,isomer #3	CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O[Si](C)(C)C(C)(C)C)[C@H]1O	2497.4	Semi standard non polar	33892256
Menthyl pyrrolidone carboxylate,1TBDMS,isomer #4	CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O[Si](C)(C)C(C)(C)C	2498.8	Semi standard non polar	33892256
Menthyl pyrrolidone carboxylate,2TBDMS,isomer #1	CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O[C@@H]1O[C@H](CO[Si](C)(C)C(C)(C)C)[C@@H](O[Si](C)(C)C(C)(C)C)[C@H](O)[C@H]1O	2772.6	Semi standard non polar	33892256
Menthyl pyrrolidone carboxylate,2TBDMS,isomer #2	CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O[C@@H]1O[C@H](CO[Si](C)(C)C(C)(C)C)[C@@H](O)[C@H](O[Si](C)(C)C(C)(C)C)[C@H]1O	2771.0	Semi standard non polar	33892256
Menthyl pyrrolidone carboxylate,2TBDMS,isomer #3	CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O[C@@H]1O[C@H](CO[Si](C)(C)C(C)(C)C)[C@@H](O)[C@H](O)[C@H]1O[Si](C)(C)C(C)(C)C	2780.2	Semi standard non polar	33892256
Menthyl pyrrolidone carboxylate,2TBDMS,isomer #4	CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O[C@@H]1O[C@H](CO)[C@@H](O[Si](C)(C)C(C)(C)C)[C@H](O[Si](C)(C)C(C)(C)C)[C@H]1O	2756.2	Semi standard non polar	33892256
Menthyl pyrrolidone carboxylate,2TBDMS,isomer #5	CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O[C@@H]1O[C@H](CO)[C@@H](O[Si](C)(C)C(C)(C)C)[C@H](O)[C@H]1O[Si](C)(C)C(C)(C)C	2759.4	Semi standard non polar	33892256
Menthyl pyrrolidone carboxylate,2TBDMS,isomer #6	CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O[Si](C)(C)C(C)(C)C)[C@H]1O[Si](C)(C)C(C)(C)C	2759.8	Semi standard non polar	33892256
Menthyl pyrrolidone carboxylate,3TBDMS,isomer #1	CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O[C@@H]1O[C@H](CO[Si](C)(C)C(C)(C)C)[C@@H](O[Si](C)(C)C(C)(C)C)[C@H](O[Si](C)(C)C(C)(C)C)[C@H]1O	3011.5	Semi standard non polar	33892256
Menthyl pyrrolidone carboxylate,3TBDMS,isomer #2	CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O[C@@H]1O[C@H](CO[Si](C)(C)C(C)(C)C)[C@@H](O[Si](C)(C)C(C)(C)C)[C@H](O)[C@H]1O[Si](C)(C)C(C)(C)C	3023.3	Semi standard non polar	33892256
Menthyl pyrrolidone carboxylate,3TBDMS,isomer #3	CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O[C@@H]1O[C@H](CO[Si](C)(C)C(C)(C)C)[C@@H](O)[C@H](O[Si](C)(C)C(C)(C)C)[C@H]1O[Si](C)(C)C(C)(C)C	3016.1	Semi standard non polar	33892256
Menthyl pyrrolidone carboxylate,3TBDMS,isomer #4	CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O[C@@H]1O[C@H](CO)[C@@H](O[Si](C)(C)C(C)(C)C)[C@H](O[Si](C)(C)C(C)(C)C)[C@H]1O[Si](C)(C)C(C)(C)C	2998.7	Semi standard non polar	33892256
Menthyl pyrrolidone carboxylate,4TBDMS,isomer #1	CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O[C@@H]1O[C@H](CO[Si](C)(C)C(C)(C)C)[C@@H](O[Si](C)(C)C(C)(C)C)[C@H](O[Si](C)(C)C(C)(C)C)[C@H]1O[Si](C)(C)C(C)(C)C	3234.6	Semi standard non polar	33892256

Spectra

GC-MS Spectra

Spectrum Type	Description	Splash Key	Deposition Date	Source	View
Predicted GC-MS	Predicted GC-MS Spectrum - Menthyl pyrrolidone carboxylate GC-MS (Non-derivatized) - 70eV, Positive	splash10-0k9i-9452000000-42588a0886876e47aa34	2017-09-01	Wishart Lab	View Spectrum
Predicted GC-MS	Predicted GC-MS Spectrum - Menthyl pyrrolidone carboxylate GC-MS (4 TMS) - 70eV, Positive	splash10-0006-3200190000-cfcaef8b68862ed10a74	2017-10-06	Wishart Lab	View Spectrum
Predicted GC-MS	Predicted GC-MS Spectrum - Menthyl pyrrolidone carboxylate GC-MS (Non-derivatized) - 70eV, Positive	Not Available	2021-10-12	Wishart Lab	View Spectrum

MS/MS Spectra

Spectrum Type	Description	Splash Key	Deposition Date	Source	View
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - Menthyl pyrrolidone carboxylate 10V, Positive-QTOF	splash10-0ap0-0904000000-5987737bc24c24d02b91	2016-08-01	Wishart Lab	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - Menthyl pyrrolidone carboxylate 20V, Positive-QTOF	splash10-0a4r-2900000000-98832b544c236461ab7b	2016-08-01	Wishart Lab	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - Menthyl pyrrolidone carboxylate 40V, Positive-QTOF	splash10-0a4r-9800000000-f8510defb41929ee73cc	2016-08-01	Wishart Lab	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - Menthyl pyrrolidone carboxylate 10V, Negative-QTOF	splash10-066r-1916000000-a378c1511bac4d5b07a1	2016-08-03	Wishart Lab	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - Menthyl pyrrolidone carboxylate 20V, Negative-QTOF	splash10-0a4i-1910000000-2399f4fa758e520d32ed	2016-08-03	Wishart Lab	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - Menthyl pyrrolidone carboxylate 40V, Negative-QTOF	splash10-0a4r-3900000000-645e98d305305d599325	2016-08-03	Wishart Lab	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - Menthyl pyrrolidone carboxylate 10V, Positive-QTOF	splash10-014i-2904000000-54f8af8655aa2de8ed16	2021-09-23	Wishart Lab	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - Menthyl pyrrolidone carboxylate 20V, Positive-QTOF	splash10-000t-9301000000-7bb143c4dbd965c6464a	2021-09-23	Wishart Lab	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - Menthyl pyrrolidone carboxylate 40V, Positive-QTOF	splash10-0002-9420000000-9b565aa778157c0d3383	2021-09-23	Wishart Lab	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - Menthyl pyrrolidone carboxylate 10V, Negative-QTOF	splash10-014i-0009000000-d77dc8a8103d351ee52a	2021-09-25	Wishart Lab	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - Menthyl pyrrolidone carboxylate 20V, Negative-QTOF	splash10-0aor-4916000000-136c5db92fabfe126e60	2021-09-25	Wishart Lab	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - Menthyl pyrrolidone carboxylate 40V, Negative-QTOF	splash10-0k9i-2900000000-496b2b88c3e880eeffbe	2021-09-25	Wishart Lab	View Spectrum

NMR Spectra

Spectrum Type	Description	Deposition Date	Source	View
Predicted 1D NMR	¹³C NMR Spectrum (1D, 100 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum
Predicted 1D NMR	¹H NMR Spectrum (1D, 100 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum
Predicted 1D NMR	¹³C NMR Spectrum (1D, 1000 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum
Predicted 1D NMR	¹H NMR Spectrum (1D, 1000 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum
Predicted 1D NMR	¹³C NMR Spectrum (1D, 200 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum
Predicted 1D NMR	¹H NMR Spectrum (1D, 200 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum
Predicted 1D NMR	¹³C NMR Spectrum (1D, 300 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum
Predicted 1D NMR	¹H NMR Spectrum (1D, 300 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum
Predicted 1D NMR	¹³C NMR Spectrum (1D, 400 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum
Predicted 1D NMR	¹H NMR Spectrum (1D, 400 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum
Predicted 1D NMR	¹³C NMR Spectrum (1D, 500 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum
Predicted 1D NMR	¹H NMR Spectrum (1D, 500 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum
Predicted 1D NMR	¹³C NMR Spectrum (1D, 600 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum
Predicted 1D NMR	¹H NMR Spectrum (1D, 600 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum
Predicted 1D NMR	¹³C NMR Spectrum (1D, 700 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum
Predicted 1D NMR	¹H NMR Spectrum (1D, 700 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum
Predicted 1D NMR	¹³C NMR Spectrum (1D, 800 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum
Predicted 1D NMR	¹H NMR Spectrum (1D, 800 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum
Predicted 1D NMR	¹³C NMR Spectrum (1D, 900 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum
Predicted 1D NMR	¹H NMR Spectrum (1D, 900 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum

Biological Properties

Cellular Locations

Cytoplasm
Extracellular
Membrane

Biospecimen Locations

Not Available

Tissue Locations

Not Available

Pathways

Not Available

Name	SMPDB/PathBank	KEGG

Normal Concentrations

Not Available

Abnormal Concentrations

Not Available

Associated Disorders and Diseases

Disease References

None

Associated OMIM IDs

None

External Links

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FooDB ID

FDB006135

KNApSAcK ID

Not Available

Chemspider ID

4573550

KEGG Compound ID

C03962

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

5459767

PDB ID

Not Available

ChEBI ID

15411

Food Biomarker Ontology

Not Available

VMH ID

Not Available

MarkerDB ID

Not Available

Good Scents ID

Not Available

References

Synthesis Reference

Not Available

Material Safety Data Sheet (MSDS)

Not Available

General References

Simons K, Toomre D: Lipid rafts and signal transduction. Nat Rev Mol Cell Biol. 2000 Oct;1(1):31-9. [PubMed:11413487 ]
Watson AD: Thematic review series: systems biology approaches to metabolic and cardiovascular disorders. Lipidomics: a global approach to lipid analysis in biological systems. J Lipid Res. 2006 Oct;47(10):2101-11. Epub 2006 Aug 10. [PubMed:16902246 ]
Sethi JK, Vidal-Puig AJ: Thematic review series: adipocyte biology. Adipose tissue function and plasticity orchestrate nutritional adaptation. J Lipid Res. 2007 Jun;48(6):1253-62. Epub 2007 Mar 20. [PubMed:17374880 ]
Lingwood D, Simons K: Lipid rafts as a membrane-organizing principle. Science. 2010 Jan 1;327(5961):46-50. doi: 10.1126/science.1174621. [PubMed:20044567 ]
(). EAFUS: Everything Added to Food in the United States.. .
Gunstone, Frank D., John L. Harwood, and Albert J. Dijkstra (2007). The lipid handbook with CD-ROM. CRC Press.

Showing metabocard for Menthyl pyrrolidone carboxylate (HMDB0032368)

MOL for HMDB0032368 (Menthyl pyrrolidone carboxylate)

3D MOL for HMDB0032368 (Menthyl pyrrolidone carboxylate)

3D SDF for HMDB0032368 (Menthyl pyrrolidone carboxylate)

3D-SDF for HMDB0032368 (Menthyl pyrrolidone carboxylate)

PDB for HMDB0032368 (Menthyl pyrrolidone carboxylate)

3D PDB for HMDB0032368 (Menthyl pyrrolidone carboxylate)

SMILES for HMDB0032368 (Menthyl pyrrolidone carboxylate)

INCHI for HMDB0032368 (Menthyl pyrrolidone carboxylate)

Structure for HMDB0032368 (Menthyl pyrrolidone carboxylate)

3D Structure for HMDB0032368 (Menthyl pyrrolidone carboxylate)

Predicted Collision Cross Sections

Predicted Retention Times

Underivatized

Predicted Kovats Retention Indices

Underivatized

Derivatized

GC-MS Spectra

MS/MS Spectra

NMR Spectra